HuntNFish referenced a blog I wrote nearly 20 years ago, and I've since learned a bit more on citric acid use. Haven't read it in a minute and I noticed some things I would have corrected in my OG article:
Citric acid should be used as tool that you rarely need, and then used sparingly and only in very specific environments/climates.
Revisiting why to use is less important than when to start, how often and when to quit use. If you use it too frequently for too long the result will be some surface spoilage (color and depth of trimming needed).
When to use: Ambient temps above 50F (bacteria starts to thrive and blow flies become active). I only recommend using IF meat is exposed to open air in sustained 50F temps. The use of citric acid is more necessary around 60F when blow flies get determined and energetic from warmth and surface bacteria become increasingly active. Blow flies may land on your treated meat surface but they won't lay eggs if the pH is < 5.5.
How often to use: Once every-other-day max and only if ambient conditions warrant and only if meat is exposed to air outside bags for hours (not minutes).
When to quit using it: After post harvest day 4 bacteria are entering death phase unless left unchecked and trimmed away, or unless new source bacteria have been introduced on the meat surface. Hunters who continue to trim surface threats daily during sensory checks should be reducing viable source threats as they present, therefore less need for citric acid follow up treatments. That means if you use it on kill site day, you might need it on Day 3 (not likely) and then discontinue.
Citric acid is a surface treatment. It's meant to shock source bacteria colonies into an unstable activity level until the hunter IDs a problem area and trims it off. Meat pH is also important to the topic of meat preservation, but citric acid has nothing to do with this factor and cannot change the acidity of muscle protein.
Soaking bags in citric acid is a total scam. Don't bother, it's the meat surface environment hunters want to manipulate not the bag it rests in. Besides, if on Day 2 you wash your bloody game bags, the citric acid will be dissolved immediately.
I'll soon drop a blog post on the Role of Muscle pH in Meat Quality: Wild Meat Preservation