I don't have specific experience with the sitka but have some with similar pieces.
I would expect the 80g of primaloft gold to be much warmer and more of a static piece for moderate weather (30F) while I'd expect the ambient in 100/150 to be more of an active piece for cold-to-cool (20F-30F).
The ambient will be more breathable since you essentially only have an outer face fabric with no inner, with the 'alpha fleece' touching your skin while the primaloft gold has the puff sandwiched between two layers of nylon.
I own the outdoor vitals pursuit hybrid (75gsm alpha fleece, hybrid with grid fleece) as well as vario (40gsm primaloft), rab generator alpine (100gsm primaloft), and Mammut rime light (40gsm primaloft, hybrid fleece, no insulation in forearms or hood).
The 75gsm alpha piece is most similar in feel to the mammut hybrid puff with 40gsm primaloft gold. The mammut feels noticably more breathable than the OV Vario despite same weight of primaloft because it doesn't have insulation in the hood, elbows down, or in the side panels from armpit to belt, just pertex in those regions. I use both of those pieces as active layers for high output activities (ski touring, biking, steep uphill hiking) that are colder than 30F. warmer than that and I'm in a sun hoodie. I also use them as active layers in moderate output activities (still hunting, walking or skiing downhill) in moderate temps (40-50F) especially with wind where they shine over a grid fleece.
The OV vario with 40gsm primaloft everywhere is more of a static piece for mild temps (40-50F) or active piece in low output (still hunting) cool-cold temps (20-30F). It's my most commonly worn around town jacket in 35-50F temps.
my 100gsm primaloft jacket is much more of a static insulation piece, too warm for any even moderate activity. I put in on for glassing, lunches, etc for temps from ~40-15F. I might be able to still hunt in it below 10F....