A lot of western shooters are so used to low humidity it freaks them out that stainless can actually rust and pit in the right conditions. Combustion of gunpowder creates all sorts of chemicals. As for the carbon flaking off the can and building up on the bolt face, that’s not news even to guys like me who don’t own one. It’s not a big leap in logic to assume some cans have carbon steel parts, or low quality stainless that rusts and rusty carbon flakes contribute to the rust color in the chamber. This is probably a farm/ranch coyote rifle with a cheap can kept vertical and bounced around every day in a side by side, tractor or jeep. It’s being a little dramatic of the guy taking the pics to not show the bolt face after being cleaned off with simple scrubbing, or not cleaning the chamber to only show pitting and not just the discoloring.
We just bought a case of Kleenex at Costco if anyone needs an extra box to get through this. You’ll be ok.