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I had the same experienceThe Mongulai socks wore through in about 8 months for me. Wore them almost daily for work though. They made my feet sweat a lot, which happens with merino too.
OP - what type of Darn Tough's have you tried? I wear the Stride Micro Crew Ultra-Lightweight Running Sock (Style 1036) with injiji synthetic liners in 8" Timberlines. Got pretty thick calves and that combo works well. Cuff of the boot is just below where my calves start to get thick and that sock pairing stays in place well without irritating my calves.